[N,N-Etheylene bis (Salicylidene iminato)](benzoyl acetonato) Iron(111) as thermal initiator of methyl methacrylate polymerization

M.A.Ibraheem; A.F.Dawood .AL-Niaimi

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[N,N-Etheylene bis (Salicylidene iminato)](benzoyl acetonato) Iron(111) as thermal initiator of methyl methacrylate polymerization

M.A.Ibraheem, A.F.Dawood .AL-Niaimi

Academic Science Journal
2010, Volume 6, Issue 2, Pages 59-69

Abstract

The polymerization of methyl methacrylate(MMA) initiated by a mixed ligandcomplex , [N,N-Etheylene bis (Salicylidene iminato)](benzoyl acetonato) Iron(111) hasbeen studied in bulk at 80◦C .The rate order of polymerization is 0.5 with respect toinitiator concentration and 1.5 with respect to monomer concentration .The activationenergy and the kinetic are evaluated .According to the experimental results obtained afree radical mechanism has been proposed.

Keywords

[N, N-Etheylene bis, Salicylidene iminato], benzoyl acetonato Iron, 111 as thermal initiator of methyl methacrylate polymerization

Year	Total	Jan	Feb	Mar	Apr	May	Jun	Jul	Aug	Sep	Oct	Nov	Dec
2023	12	1			1		2		2	1	2	3
2022	33	2	2	4	3	2	5	4	4	3	1	3
2021	38	2	5	3	2	8	12		1	1			4
2020	26	1	1	6	3	1	2		3	1	4	3	1
2019	18	1		3	1	2	3	1	1	2	2		2
2018	12	1		1	1	1	3			1		1	3
2017	17		1		1	2	2	2	2		1		6
2016	22	1	2	4	2		2		3	3	3	1	1
2015	22	1		3	3	1	4			1	4	3	2
2014	46	5	2	3	2	5	7	5		1	5	1	10
2013	131	4	9	4	14	26	9	11	10	18	5	14	7
2012	18							3	1	1	8	2	3

[N,N-Etheylene bis (Salicylidene iminato)](benzoyl acetonato) Iron(111) as thermal initiator of methyl methacrylate polymerization

Abstract

Keywords

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