Synthesis and ldentification of metal complexes of 1- phenyl -3, (2'(S'phenyl amine)'l, 3, 4-thiad iazole'Z'yl) phenyl thiourea.

Abstract

Complexes of 1-phenyl-3-(2(-5-(phenyl amino)-1,3,4-thiadiazole-2-yl)phenyl) thiourea have been prepared and characteizedby elemental analysis, Ff-[R, and u.v./ visible spectra moreover,determination of metal content M%o by flame atomic absorptionspectroscopy, molar conductance in DMSO solution and magneticmoments (peffl.The result showed that the ligand (L) was coordinated to Mn*2, Ni*2,Ct*2,2n*2,Cd*2, and Hg*2 ions through the nitrogen atoms and sulpheratoms.From the result obtained, rhe following general formula [MLClz] hasbeen given for the prepared complexes with an octahedral geometryaround the metal ions for all complexes.where M= Mn*2, Ni*2, cu*2, zn*z, cd*z, and Hg*2l= l-phenyl-3-(2-(5-(phenyl amino)-1, 3, 4- thiadiazole-2-yl)phenyl) thiourea.N_こ_樹Namino)-1, 3, 4- thiadiazole-2-yl) phenyl) I -phenyl-3-(2-(5-(phenylthiourea [L]