TY - JOUR ID - TI - Synthesis and Characterization of Palladium (II) Complexes Containing Mixed Ligands with Pyrrolidine Dithiocarbamate and Phosphines AU - Mousa. S. Hussein PY - 2018 VL - 21 IS - 2 SP - 18 EP - 27 JO - Al-Nahrain Journal of Science مجلة النهرين للعلوم SN - 26635453 26635461 AB - This work includes preparation and characterization of new four mono nuclear complexes of palladium metal ion result from treating palladium chloride with ammonium pyrrolidine dithiocarbamate (PDTC), tertiary phosphines(dppe, dppp) and 2-phenyl pyridine (Hppy) in different molar ratios. All complexes have been characterized by spectroscopic methods{IR, UV-Vis, 1HNMR} spectroscopy, in addition to elemental analysis (C.H.N) and conductivity measurement. pyrrolidine dithiocarbamate‎ ligand behaves like bidentate in the complexes [Pd(PDTC)(dppe)]Cl and [Pd(PDTC)(ppy)] but it behaves as mono dentate in the complexes [Pd(PDTC)2(dppp)] and [Pd(PDTC)2(dppe)], while tertiary phosphines and 2-phenyl pyridine behave like bidentate ligand.

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