DETERMINATION OF TRACE METALS INMAHAWEEL RIVERSEDIMENTS BY ACID EXTRACTION

Abstract

Abstract
In this study, a boiling mixture of acids (20% HCl + 80% HNO3) was used to extract trace
metals from sediments for Mahaweel River (branch of Euphrates). The elements of interest included
Na, Mg, Ca, Cr, Cu, Pb, Hg and Ni, all of which can be determined by electro thermal atomic
absorption spectrometry (ETAAS). High recoveries percentage 96, 97, 99, 99, 97.5 and 95 for Na,
Mg, Ca, Cr, Cu, and Pb, respectively. The relative standard deviation of the method is less than
3%. Calibration graphs for Pb, Ni and Cr were found to be linear between 100-250, 80-180, 180-
250 ng/mL, respectively However, when the acid extraction method was applied to some selected
sediments, the resulting trace metal concentrations, although reproducible. Apparently SRM-1645
provided too favorable an assessment of the true accuracy of the method with ordinary sediments.