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Iraqi Journal of Chemical and Petroleum Engineering

المجلة العراقية للهندسة الكيمياوية وهندسة النفط

ISSN: 19974884
Publisher: Baghdad University
Faculty: Engineering
Language: Arabic and English

This journal is Open Access

About

The Iraqi Journal of Chemical and Petroleum Engineering is a quarterly peer-reviewed scientific journal that was established in 2000 by the College of Engineering of the University of Baghdad. The Iraqi Journal of Chemical and Petroleum Engineering receives citations in the category of Chemical and Petroleum Engineering and relevant subjects.

Aims
The Iraqi journal of chemical and petroleum engineering is Open Access journal dedicated to publishing peer-reviewed research articles with respect to the subjects in fields of chemical and petroleum Engineering. In particular, petrochemical, biochemical, water treatment, electrochemical, petroleum and natural gas production and technology, and environment are the major interest of the journal. The journal aims to provide a free platform for the researches all over the world to share diverse types of knowledge and discuss the recent developments in the subjects related to the journal interest.

Objective
Objective of the journal is to promote the researches in the engineering subjects covered by journal to dissemination their intellectual products to the global community free of restriction. That achieves by making all of published articles available free of cost for all researcher through adopting Open Access publication model.

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Contact info

Aljadreah, Baghdad
Iraq
P.O Box: 47024
Phone: +964-1-7781506
Email: ijcpe@coeng.uobaghdad.edu.iq
ijcpe@yahoo.com

Table of content: 2012 volume:13 issue:1

Article
Extraction of Pelletierine from Punica granatum L.by Liquid Membrane Technique and Modelling

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Abstract

This work was conducted to study the extraction of pelletierine sulphate from Punica granatum L. roots by liquid membrane techniques. Pelletierine sulphate is used widely in medicine. The general behavior of extraction process indicates that pelletierine conversion increased with increasing the number of stages and the discs rotation speed but high rotation speed was not favored because of the increased risk of droplet formation during the operation. The pH of feed and acceptor solution was also important. The results exhibit that the highest pelletierine conversion was obtained when using two stages, (10 rpm) discs speed of stainless steel discs, (pH=9.5) of feed solution and (pH=2) of acceptor solution in n-decane. Assuming the existence of two thin reaction layers in the feed and stripping solutions, mathematical model was developed to describe the pelletierine transport. On the basic of the experimental data obtained under various conditions and the model proposed, it was found that the solute transfer into the liquid membrane is mainly diffusion-controlled.يهدف هذا البحث الى دراسة استخلاص دواء الݒلترين سلفيت من جذور نبات الرمان بأستخدام تقنيات السائل الغشائي. الݒلترين يستخدم بصوره واسعه في الطب ,حيث يستخدم للقضاء على الديدان الشريطيه والديدان المعويه وكعلاج للاسهال و الدازنتري ,وكمضاد بكتيري. وبينت الدراسات الحديثه بأنه يستعمل كمضاد فطري عندما يمزج مع الاملاح الحديديه , وهذه المجموعه نفسها استعملت لاختبار تأثيره على نمو فيروس الايدز. السلوك العام لعملية الاستخلاص يشير الى ان تحول الݒلترين يزداد عند زيادة عدد المراحل وسرعة دوران الاقراص لكن السرع العاليه كانت غير مفضله بسبب تكون قطرات على الاقراص وبالتالي نقصان بالمساحه السطحيه للطبقات المتجدده. ولكن درجة الحامضيه للمحلول الداخل والمستلم كانت محكومه ضمن حد معين. اظهرت النتائج ان اعلى تحول للݒلترين تم الحصول عليه عند استخدام مرحلتين , سرعة دوران الأقراص (10 دوره / دقيقة) و درجة الحامضية للمحلول الداخل =9.5 , درجة الحامضيه للمحلول المستلم = 2 وبأستخدام الديكان كسائل غشائي . تم تطوير موديل رياضي لوصف عملية انتقال الݒلترين على افتراض وجود طبقتي تفاعل رقيقه في المحلول الداخل والمستلم . على اساس البيانات التجريبيه التي تم الحصول عليها والنموذج الرياضي المقترح وجد ان انتقال المذيب الى الغشاء السائل مسيطر عليه بشكل اساسي من قبل الانتشار.


Article
Production and Evaluation of Biodiesel from Sheep Fats Waste

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Abstract

Animal fats are a good, promising and ethical alternative source for biodiesel production, but they need more complex treatments than vegetable oils. Iraqi butchery plants waste fats (sheep fat) which are suggested as feedstock to produce biodiesel. This type of fat contains a large quantity of free fatty acids (FFAs) (acid number 49.13 mg KOH/g of fat). The direct transesterification of such fats produce high amount of soap instead of desired biodiesel, so a pre-treatment step (to reduce FFAs) is necessary before transesterification. This step was done by esterification of the free fatty acids in the fat by adding ethanol and using 1% acid catalyst (H2SO4) for 30 minutes. The results showed that the acid number of sheep fat after pre-treatment step reduced to 0.97 mg KOH/g of fat at esterification step. Transesterification of treated fats (produce from esterification) used to convert biodiesel. The maximum yield of biodiesel was about 85 vol. % for treated fats obtained with 25/100 ethanol/fat wt. ratio, 70° C reaction temperature and 50 minutes total treatment period (pre-treatment step and transesterification reaction). The suggested model of the production rate kinetic of transesterification reaction, found that the production rate is inversely proportional with the volume of biodiesel produced with activation energy of 25320 J/mole.


Article
Enhancement of Biogas production and organic reduction of sludge by different pre-treatment processes

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Abstract

Anaerobic digestion (AD) is the most common process for dealing with primary and secondary wastewater sludge. In the present work, four pre-treatment methods (ultrasonic, chemical, thermal, and thermo-chemical) are investigated in Al-Rustumya Wastewater Treatment plant in order to find their effect on biogas production and volatile solid removal efficiency during anaerobic digestion. Two frequencies of ultrasonic wave were used 30 KHz and 50 KHz during the pre-treatment. Sodium hydroxide was added in different amounts to give three pH values of 9, 10 and 11 in chemical pre-treating processes. The sludge was heated at 60oC and 80oC through thermal pre-treatment experiment. Also, the sludge was treated thermo-chemically at 80 oC and pH 11 prior to anaerobic digestion. Maximum biogas production (6009 ml) was obtained at ultrasonic pre-treatment method with 30 kHz. The volumetric ratio of produced biogas to the initial volume of sludge is about 4:1.


Article
Numerical Analysis of Laminar Natural Convection in Square Enclosure with and without Partitions and Study Effect of pPartition on the Flow Pattern and Heat Transfer

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Abstract

The problem of steady, laminar, natural convective flow in an square enclosure with and without partitions is considered for Rayleigh number (103-106) and Prandtl number (0.7). Vertical walls were maintained isothermal at different temperatures while horizontal walls and the partitions were insulated. The length of partition was taken constant. The number of partitions were placed on horizontal surface in staggered arrangement from (1– 3) and ratio of partition thickness (H/L= 0.033, 0.083, 0.124). The problem is formulated in terms of the vorticity-stream function procedure. A numerical solution based on a program in Fortran 90 with the finite difference method is obtained. Representative results illustrating the effects of the thickness and number of partitions on the contour maps of the streamlines and temperature are reported and discussed. In addition, the local Nusselt number is evaluated. Results show that the values of stream function (the strength of flow) in enclosure increases with the increasing Rayleigh number. As the number of partitions and thickness of partition increases, the strength of flow decreases. Mean Nusselt number increases with increasing Rayleigh number at different number of partitions. The numerical results are compared with available numerical results and experimental data and a good agreement is obtained.يتضمن البحث الحالي دراسة نظرية عددية لانتقال الحرارة بالحمل الحر للجريان المستقر داخل حيز مربع بوجود او عدم وجود الحواجز.الدراسة تغطي المدى لرقم رايلي من103 الى 106 ولعدد برانتل ((Pr=0.7.الجدران العمودية للحيز ذات درجات حرارة ثابتة لكن مختلفة بينما الجدران الافقية معزولة. ارتفاع الحواجز الموضوعة داخل الحيز ثابت وموضوعة على الجدران الافقية بترتيب متخالف وباعداد مختلفة تتراوح من( 1- 3 ) وسمك الحواجز المسخدم تساوي(H/L=0.033, 0.083, 0.124) . الحل العددي تم باستخدام طريقة دالة الانسياب- الدوامّية بأستخدام طريقة الفروق المحددة مع بناء برنامج حاسوبي بلغة(فورتران 90). تم دراسة تاثير كل من رقم رايلي ، عدد الحواجز ، وسمك الحواجز على شدة الدوامات الدوارة و انتقال الحرارة داخل الحيز . بالاضافة الى ذلك تم ايجاد معدل قيم رقم نسلت. بينت النتائج ان شدة الدوامات الدوارة تزداد مع زيادة عدد رايلي بينما تقل عند زيادة عدد الحواجزاو سمك الحواجز . كذلك بينت النتائج ان متوسط نسلت يزداد مع زيادة رقم رايلي. وتم مقارنة النتائج العددية مع النتائج العددية والعملية المتوفرة وكانت نتائج المقارنة جيدة.

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