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Synthetic & Analytic Study of Complexes of Some Transition Elements with 5-Phyenyl Amino-3-Salicylidimino- 1,2,4 Thiadizole
دراسة تحضيرية وتحليلية لبعض مركبات العناصر الانتقالية مع 5ـ فنيل أمينو -3- ساليسالديمينو-1 ، 2 ، 4 ثايادايازول

Authors: Mr. Khalaf Faris As-Samarri --- Dr.Mahmoud Najim Al-Jibouri
Journal: Journal of Surra Man Raa مجلة سر من رأى ISSN: 18136798 Year: 2006 Volume: 2 Issue: 3 Pages: 156-171
Publisher: University of Samarra جامعة سامراء

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Abstract

The new Schiff base 5-phyenyl amino-3-Salicylidimino- 1,2,4 thiadizole (HL) was prepared from condensation reaction of 3-amino-5-phenyl amino-1,2,4-thiadiazole with salicyldehyde. Complexes with some selected metal ions Cr(III) ,Fe(III), Zr(IV), pd(II) and pt(IV) were prepared by reacting the ligand with the hydrated metal chlorids CrCl3.6H2O , FeCl3.6H2O , ZrOCl28H2O , PdCl2 ...and K2PtCl4. 2H2O in the presence of 5% triethyl amine solution Et3N. The elemental analysis (C.H.N.M), electronic spectra (Uv-Vis spectra) showed that molar ratio of metal : ligand was 1:2. The F.T.I.R. spectra , Molar conductivity ( Λm ) and magnetic susceptibility of complexes were also determined .

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