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The vertical distribution of the electric field enhancement produced by optical antennas could be experimentally confirmed. The combination of the antenna and a quantum cascade laser would yield attractive mid-infrared microscopic analysis to detect a solid state surface. In this work, slot antenna arrays were formed on a thin Al2O3 layer grown by atomic layer deposition on a silicon substrate. Reflectivity spectra measured in the mid-infrared range showed characteristic aspects, presumably caused by the surface phonon polariton of a SiO2 layer naturally formed on the Si substrate. When the Al2O3 layer thickness was 6 nm, such spectral features disappeared. In this way, we could estimate experimentally the electric field distribution normal to the surface of the substrate.
Copper oxide --- Catalyst --- XAFS --- Electron yield detection
In this work, the in-situ x-ray absorption fine structure cell was developed for the conversion electron yield detection to characterize active metal species under reaction gas atmosphere. The probe depth was estimated to be about 9 nm at the Cu K edge. The in-situ conversion electron yield cell was applied to the shape-controlled γ-Al2O3-supported Cu2O catalyst. The reduction to Cu(0) by H2 of octahedral Cu2O particles proceeded at lower temperature than cubic particles, indicating that the surface atomic arrangement affects to the redox reaction of solid particles.
Copper oxide --- Catalyst --- X-ray absorption fine structure --- Electron yield detection
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