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A Kinetic and Mechanistic study of the Effect of the Substituent on the Rate of Reduction of PX-ArTeCl3

Author: Massarra Majid Ibrahim
Journal: Al-Fatih journal مجلة الفتح ISSN: 87521996 Year: 2005 Volume: 1 Issue: 22 Pages: 22-32
Publisher: Diyala University جامعة ديالى

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Abstract

The effect of the substituent on the rate of reduction of PX-ArTeCl3 (X=H, OH, OCH3, OC2¬H¬5) has been investigated kinetically. The reduction obeys a second order rate law and hammett equation, it is a first order in each of the oxidizing and reducing agents. The rate and δP Values of the reaction have been determined. It is found that the rate of reduction increases in the order, H<

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PX-ArTeCl3

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