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In current work the effect of addition CuO nanoparticles to the polyalkylene glycol (PAG) water solution quenching media on some properties of medium carbon steel was examined. Five cooling media was used to quenching the steel: water, 5 and 10 % water solution of polyalkylene glycol, and 5 and 10 % water solution of polyalkylene glycol with addition of 1% of CuO nanoparticles. In addition, in this study, the cooling curves for these media and the properties of tensile and affect for quenched and unquenched medium carbon steel were studied and evaluated. The results showed that the addition of CuO nanoparticles strongly improve the quenching media features and contribute to reduce water quenched sample defects (such as distortion and cracking), while at the same time still maintaining the desired mechanical property improvements. The experimental observations indicate that samples quenched 5% polyalkylene glycol water solution of with 1% CuO nanoparticles brought the best combination of mechanical properties.
Impact test --- Quenching medium --- Polymer quenching medium --- Tensile strength.
In quenching process many parameters have an effect on this process such as steel type, quenching medium type, quenching medium temperature and the volume of the workpiece. In order to give a workpiece free of defect, it’s very important to understand the effect of these parameters on this process. In the present work a mathematical heat transfer model have been used to simulate the heat treatment (quenching process). This model used to investigate the temperature distribution in the workpiece at different time. A numerical scheme based on a control volume formulation and a computer program with C++ language was used to solve the set of heat transfer equations. The developed model was used also to evaluate the effect heat treatment parameters such as quenching media, carbon steel type and cross sectional area of the workpiece. The model also can be used to simulate the heat treatment process (quenching process) of various materials and alloys with different conditions. The results of the model were compared with experimental published data give good agreement.
هنالك عوامل كثيرة تسيطر على عملية الاصلاد بالتقسية والمنتج من هذه المعاملات ومن اهم هذه العوامل هي نوعية الفولاذ او نوع المعدن , نوع وسط التبريد ودرجة حرارته وكذلك حجم القطعة المعاملة حراريا.لذلك من الضروري جدا معرفة تاثير هذه العوامل للحصول على منتج خالي من العيوب قدر الامكان وباقل جهد عملي. في هذا البحث تم وضع انموذج رياضي لوصف عملية الانتقال الحراري خلال عملية الاصلاد بالتقسية لانواع مختلفة من الفولاذ , حيث تم استخدام هذا الانموذج المقترح لمعرفة وفحص توزيع درجات الحرارة في القطع المعاملة حراريا وتاثير العوامل المذكورة في اعلاه وبالفترات الزمنية المختلفة. تم استخدام الطرق العددية لايجاد الحلول النهائية للمعادلة الخاصة بابانموذج الرياضي وكذالك تم بناء برنامج بلغة الـ C++ لايجاد الحلول لهذه المعادلات.باستخدام هذا النموذج تم دراسة تاثير العوامل التي تتحكم بالمعاملات الحرارية بصورة عامة وعملية الصلاد بصورة خاصة وقد استخدم هذا الانموذج ايضا بدراسة عملية الاصلاد لمعادن اخرى غير الفولاذ حيث اظهرت المقارنة بين نتائج البحث الحالي مع نتائج عملية منشورة اظهرت تطابق جيد بينهما.
High temperature superconductor with nominal composition Bi1.6Pb0.4Sr1.8Ba0.2Ca2 Cu3O10+ was prepared by solid state reaction method. Two sets of samples have been prepared .The first one was quenched in air; the second set was quenched in liquid nitrogen. X-ray diffraction analyses showed an orthorhombic structure with two phases, high –Tc phase (2223) and low-Tc phase (2212) in addition to that impure phase was found. It has been observed that quenched in air samples display a sharp superconducting transition and a higher-Tc phase than that of the quenched in liquid nitrogen samples.
تم تحضير المركب Bi1.6Pb0.4Sr1.8Ba0.2Ca2Cu3O10+ الفائق التوصيل بطريقة تفاعل الحالة الصلبة.حضرت مجموعتين من العينات ودرست ظروف التبريد واختلاف زمن التلبيد حيث تم تبريد عينات المجموعة الاولى في الهواء بينما بردت عينات المجموعة الثانية في سائل النيتروجينبينت تحليلات حيود الأشعة السينية ان جميع العينات لها تركيب المعيني القائم وبطورين، الطور الفائق التوصيل العالي (2333) والطور الفائق التوصيل الواطىء (2212) مع وجود طور الشوائب. .ولوحظ ايضا ان العينات المبردة سريعاً بالهواء اظهرت انتقال حاد من حالة التوصيل الاعتيادي الى حالة التوصيل الفائق وبدرجة حرارة حرجة اعلى من العينات المبردة في سائل النيتروجين.
The goal of this study is to specify the optimal factors for the hardening process (tempering temperature, the percentage of nanoparticles, type of base media, nanoparticles type and tempering time) in order to maximize the hardness of medium carbon steel by using Taguchi technique. An (L18) orthogonal array was chosen for the design of the experiment. The optimum process parameters were determined by using signal-to-noise ratio(larger is better) criterion. The important levels of process parameters on hardness were obtained by using analysis of variance which applied with the help of (Minitab17) software to investigate the effect of parameters on the hardness. Percentage of volumetric fractions of nanoparticles with three different levels (0.01, 0.03 and 0.08%) was prepared by dispersing nanoparticles that are (α-Al2O3, TiO2 and Cuo) with base fluids (De-ionized water, salt solution, and engine oil). Medium carbon steel specimens were suffered to hardening and tempering heat treatment process. Tempering temperature was (400℃, 550℃) for (30,45and 60 minutes). Results ended up with a conclusion that tempering temperature (400℃) had the major influence on hardness behavior then type of nanoparticles (TiO2) followed by time tempering (30min) then base media (salt solution) and finally volume fraction of nanoparticles (0.03%).
Nanofluids --- quenching --- hardness --- Taguchi technique.
Abstract The behavior of the absorption and fluorescence emission processes for some bis-1, 3, 4-oxadiazole sulphonyl compounds were studied in toluene, ethanol and di-methyl sulfoxide solvents. Fluorescence quenching processes of the compound bis- [2, 2/-5 ethyl sulphonyl-1, 3,4-oxadiazole]-1,4-butane, (4-Et), in toluene and ethanol using benzonitrile and benzophenone quenchers were studied too. The complex quenching mechanism of 4-Et by benzophenone, according to the obtained data, was proposed.
الخلاصه سلوك عمليات الأمتصاص والأنبعاث الضوئي لعدد من مركبات 4,3,1, -أوكسادايزول سلفون قد تمت دراسته في مذيبات التولوين ، الأيثانول وثنائي مثيل سلفوكسايد .كما درست عمليات تثبيط فلورة المركب ثنائي ] 2-2 - 5 –أثيل سلفونيل- 4,3,1 –أوكسادايزول [ -4,1 بيوتان، ( 4-Et )، في مذيب الأيثانول بأستعمال مثبط البنزوفينون ، وفي مذيب التولوين مع المثبط- البنزونايترايل . وفي ضوء النتائج المستحصله من التثبيط تم اقتراح ميكانيكيه لعملية تثبيط فلورة المركب ( 4-Et ) عند تسحيحه بمحلول البنزوفينون .
Fluorescence --- Excitation --- Quenching --- Complex --- Intersystem crossing
A study has been made to evaluate wear behavior of AISI 52100 steel underdifferent quenching media. This investigation was accomplished by two stages. Inthe first stage of the study , quenching treatment was applied to the steel alloy andthen cooling was carried out in various media (Oil , Polyvinyl Alcohol , Glycerol),and finally low temperature tempering (200Co) was applied to the quenchedsamples to eliminate internal stresses after transformation from austenizationtemperature to the temperature which the samples were cooled. Microstructuralexamination was achieve using light microscopic for all heat treated specimens aftermetallographic preparations . In the second stage , pin - on - disk technique wasused to determine the wear rate of the treated specimens depending on weight lossmethod . Worn surfaces of the steels were examined using light microscopic tocharacterize the topography of the surfaces.The results exhibited that (i) Martensitic matrices with retained austenite can beobtained depending on the quenching medium . (ii) Chromium carbides have beenprecipitated as a result of quenching heat treatment in different quenchants . (iii)Quenching in oil and then tempering revealed wear resistance more than otherquenchants . (iv) wear cracks were presented on the worn surfaces of the steelswhich was used in this work .
This paper goals to investigate the plasticity of Medium Carbon Steel (AISI CK45) treated by three of Quenching ( Salty . Acid and Base ) media , the sample was selected with length (100 mm) and (10 mm) diameter , has been prepared in the form of a shaft , (24) samples were immersed in different media for (100) hours, the conclusion that the quenching process of ( AISI CK 45 ) at salty (NaCl) media at a concentration of (5%) will give a high plasticity .
يهدف البحث الحالي الى دراسة تأثير ثلاثة اوساط تقسية ( ملحية ، قاعدية ، حامضية ) على لدونة الفولاذ المتوسط الكربون نوع ( فولاذ سي كي 45 ) والبنية المجهرية له من خلال استخدام معادلات النسبة المئوية للنقص في مساحة المقطع العرضي والتغير في الطول لعينة شد اعدت لاغراض البحث بواقع 12 عينة لاختبار الشد و12 عينة لفحص البنية المجهرية ، وكانت استنتاجات الدراسة الحالية اثبتت ان المحلول الملحي هو المحلول الذي يعطي لدونة اكبر
Quenching --- salty --- acid --- and Base medias
The purpose of this study is designate quenching and tempering heat treatment by using Taguchi technique to determination optimal factors of heat treatment (tempering temperature, percentage of nanoparticles, type of base media, nanoparticles type and tempering time)for increasing ultimate tensile strength, yield strength and ductility properties of medium carbon steel. An (L18) orthogonal array was chosen for the design of experiment. The optimum process parameters were determined by using signal-to-noise ratio (larger is better) criterion. The importance levels of process parameters on tensile properties were obtained by using analysis of variance, which applied with the help of (Minitab18) software. Percentage of volumetric fractions of nanoparticles with three different levels(0.01, 0.03 and 0.08 %) were prepared by dispersing nanoparticles that are (α-Al2O3,TiO2 and CuO) with base fluids (De-ionized water, salt solution and engine oil).Medium carbon steel specimens were suffered to hardening and tempering heat treatment process. The variables of tempering heat treatment were temperatures (400 C˚, 550 C˚) and a soaking times (30, 45 and 60 minutes) respectively. Tensile testing performed on samples using united universal hydraulic machine. The results for ( S/N) ratios showed the order of the factors in terms of the proportion of their effect on ultimate tensile strength, yield strength and ductility properties as follow: Tempering temperature ( 400 C˚) ,Nanoparticles type (TiO2 ),Tempering time (30 min),Type of base media (salt solution, engine oil) and Percentage of nanoparticles ( 0.03%) was the least influence for ultimate strength and yield strength while for the elongation were as follows: Tempering temperature (550 C˚),Tempering time(60min), Nanoparticles type (CuO),Type of base media (deionized water) and last percentage of nanoparticles (0.08%).
Nanofluids --- quenching --- tempering --- tensile properties --- Taguchi technique.
The present investigation aims to study the effect of heat treatment by quenching in different quenching media (salt water, water and oil) following by tempering on wear resistance of EN25 steel. EN25 steel is an alloy of medium carbon low alloy steel which is used for many applications requiring high tensile strength and wear resistance such as connecting rods, adapters and in power sectors extensively. The specimens are machined to 20 mm in length and 10 mm in diameter. This study is done by two stages: The first stage is done by austenitizing EN25 steel to 850℃ for 1 hr by quenching the specimens in three different quenching media and then tempered at 300℃ in air. While the second stage is performed by wear test. Dry sliding wear test is done by using pin –on-disc technique by varying the loads as 5, 10, 15, 20 and 25 N, also varying the time as 5, 10, 15, 20, 25 and 30 min respectively. The microstructure examination, hardness and followed roughness tests are also done for the specimens before and after wear test. The results of this work showed that an improving in wear resistance and hardness for the specimen quenched by salt water more than for water and oil. At the same time the roughness decreasing for the specimen quenched by salt water more than for water and oil.
يهدف البحث الحالي لدراسة تأثير المعاملة الحرارية بالتقسية في اوساط مختلفة (ماء مالح، ماء، زيت) على مقاومة البلى للفولاذ En 25 . الفولاذ En 25 هو سبيكة من فولاذ متوسط الكاربون منخفض السبائكية يستخدم في عدة تطبيقات التي تتطلب مقاومة شد ومقاومة بلى عاليتين مثل اذرع التوصيل ،المحولات وقاطعات القدرة. تم تشغيل العينات بطول 20 ملم وقطر 10 ملم . اجريت هذه الدراسة بمرحلتين: الاولى تم فيها تقسية العينات بثلاث اوساط تقسية مختلفة عند درجة حرارية 850 مo ولمدة 1 ساعة، بعد ذلك تتم عملية المراجعة عند 300 مo ولمدة 1 ساعة ومن ثم التبريد في في الهواء. بينما في المرحلة الثانية اجري اختبار البلى. تم اختبار البلى الانزلاقي الجاف باستخدام تقنية المسمار- على- القرص وذلك بتغير الاحمال 25،20،15،10،5 نيوتن، كذلك تم تغير الزمن بمقدار 30،25،20،15،10،5 دقيقة على التوالي. وكذلك تم فحص البنية المجهرية واجريت اختبارات الصلادة والخشونة قبل وبعد اختبار البلى.اظهرت نتائج البحث تحسن في مقاومة البلى والصلادة للعينة المقساة بالماء المالح اكثر مما هو عليه للعينات المقساة بالماء والزيت. وبنفس الوقت نقصان الخشونة للعينة المقساة بالماء المالح اكثر مما هو عليه للعينات المقساة بالماء والزيت
EN25 steel --- quenching heat treatment --- quenching media --- wear. --- ولاذ EN25 --- معاملة حرارية بالتقسية --- أوساط التقسية --- البلى.
The Al-Cu aluminum alloys are primarily used in the aerospace industry as structural components. This study aim to improve properties of Al-4.3%, Cu-0.7%, Fe-0.6%, Mg alloy such as compression resistance, thermal stability and microstructure by quenching in 30% polyethylene glycol. Results showed that compression resistance improved by (10%) when quenching in 30% polyethylene glycol corresponding to the base alloy (quenching in water) when aging at 175 ºC for 3 hour. Also results showed that the thermal stability improved when quenching in polyethylene glycol.
إن سبيكة (Al-Cu) مِنْ ِ سبائكِ الألمنيومِ التي تستعملُ في صناعة المركبات الفضائيةِ كمكوّنات هيكلية . إن الهدف من هذه الدراسةِ هو تَحسين خواص سبيكة (Al-4.3%Cu-0.7%Fe-0.6%Mg) مثل مقاومة الانضغاط , الاستقرارية الحرارية من خلال استخدام الإخماد في البولي اثيلين كلايكول لهذه السبيكةِ. أظهرت النتائج إن السبيكة يحدث فيها تحسنا كبيرا في الاستقرارية الحرارية وكذلك تحسن في مقاومة الانضغاط بنسبة (10%) عند الإخماد في (30%) من البولي اثيلين كلايكول بالمقارنة عند الإخماد عند إجراء التعتيق في درجة ºC 175 .
Effect of Quenching --- Polyethylene Glycol --- PAG --- Aluminum Alloy
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